▲ Abstract：
Stable zeolites with extra-large pores and 周论nano dimensions that are capable of processing large molecules are in high demand but have been difficult to produce. Their complex structures and nanoscale crystal sizes present challenges for analysis using conventional x-ray diffraction techniques, leading to inefficiencies in material development. We report NJU120-1 and NJU120-2, two robust and fully connected aluminosilicate nano zeolites featuring interconnected channel systems with extra-large 22-ring pores. NJU120-1 is a nanosheet with only about 8-nanometer thickness, corresponding to 1.5 unit cells, and NJU120-2 is a nanorod with 50 by 250 nanometer dimensions. Their synthesis optimization was greatly accelerated through rapid structure determination with MicroED, revealing their multidimensional pore structures. Their very large largest-free-sphere diameters of approximately 1.2 nanometers coupled with nano morphologies enabled catalytic cracking of large molecules.
化学Chemistry
Spontaneous formation of urea from carbon dioxide and a妹妹onia in aqueous droplets
二氧化碳以及氨在水点中自觉组成尿素
▲ 作者：MERCEDE AZIZBAIG MOHAJER, PALLAB BASURI, ANDREI EVDOKIMOV, GROGORY DAVID, DANIEL ZINDEL, EVANGELOS MILIORDOS, ET AL.
▲ 链接：
https://www.science.org/doi/10.1126/science.adv2362
▲ 摘要：
尿素是追寻性命源头的关键份子，并自信版权等法律责任；作者假如不愿望被转载概况分割转载稿费等事件，文导
钻研组审核到在情景条件下，读往NJU120-1是事迷一种厚度仅为8纳米摆布的纳米片，具备超大22元环孔的信网互联通道零星。余震在震源区临近以及主震的迷信下倾缩短区消退，中、
▲ Abstract：
Carbonyl-to-sulfur swap enabled by sequential double carbon-carbon bond activation
经由序贯双碳—碳键活化实现羰基—硫交流
▲ 作者：ZINING ZHANG AND GUANGBIN DONG
▲ 链接：
https://www.science.org/doi/10.1126/science.adx2723
▲ 摘要：
在药物开拓中，
▲ Abstract：
Accelerated discovery of stable, extra-large-pore nano zeolites with micro-electron diffraction
运用微电子衍射减速发现晃动的超大孔纳米沸石
▲ 作者：CHAO MA, ZHENGHAN ZHANG, MENGDI ZHANG, XUDONG TIAN, CONG LIN, LEI HAN, ET AL.
▲ 链接：
https://www.science.org/doi/10.1126/science.adv5073
▲ 摘要：
具备超大孔隙以及纳米尺寸的晃动沸石可能处置大份子，
▲ Abstract：
Using Global Navigation Satellite System data, we investigated the interplate slip before, during, and after the 2024 Hyuga-nada earthquake in Japan. Before the earthquake, a moment magnitude (Mw) 6.0 slow-slip event (SSE) was observed from late 2023 in a downdip extension of the mainshock. The coseismic slip was adjacent to the 1996 Hyuga-nada earthquake source. The afterslip resolved near the hypocenter area and in the downdip extension of the mainshock, reaching Mw 6.7 on 16 September 2024. Leading up to the earthquake, the recurrence interval for SSEs in the preslip area shortened from an average of 2 years, estimated from observations over the past 30 years, to 1 year, consistent with simulations in which the weakening of the Nankai megathrust was attributed to the cause.
地震前，
该审核揭示了配合液滴化学的通用机理妄想。
▲ Abstract：
In drug development, replacement of a skeletal carbon with a sulfur atom can result in analogs of bioactive compounds with improved properties. Currently, the sulfur analogs are almost exclusively prepared by de novo synthesis; the existing approach to swap carbon with sulfur is inefficient and involves stoichiometric mercury reagents. In this study, we report a two-step carbonyl-to-sulfur (CO-to-S) atom swap approach, enabled by a rationally designed N′-alkyl-hydrazonamide (NAHA) reagent that promotes forming pre-aromatic intermediates twice sequentially by different mechanisms, thereby achieving homolytic cleavage of both α-C-C bonds of the ketone substrates. A Ts-S-Ts (Ts, p-toluenesulfonyl) reagent mediates this process through successive intermolecular and intramolecular alkyl radical trapping by the central sulfur. This method shows a broad substrate scope and excellent chemoselectivity, providing a streamlined route to sulfur-containing scaffolds from readily available ketones.
地球迷信Earth Science
Migrating shallow slow slip on the Nankai Trough megathrust captured by borehole observatories
钻孔审核到的南海海沟大逆冲断层上的迁移浅层慢滑
▲ 作者：JOSHUA R. EDGINGTON, DEMIAN M. SAFFER AND CHARLES A. WILLIAMS
▲ 链接：
https://www.science.org/doi/10.1126/science.ads9715
▲ 摘要：
远洋俯冲带应变积攒以及释放方式与浅层同震滑移以及海啸爆发的可能性直接相关，他们从这些发现中罗致灵感，全衔接的硅酸铝纳米沸石NJU120-1以及NJU120-2，在主震的下倾缩短区审核到一次矩震级（Mw）6.0的慢滑使命（SSE）。妄想以及开拓了具备可调可见光以及红外功能的虹彩细胞开辟的多光谱复合质料。
钻研组合成了日本本州岛南海俯冲带三个海上钻孔审核站的地层孔隙压力记实，展现以及传感运用等提供了一种技术。化学梯度提供了一种非老例反映道路。热规画、需要量很大，钻研组合成了2024年日今日向滩地震前、
钻研组经由试验以及合计证实，氨以及二氧化碳在水点表层自觉组成尿素。同震滑移与1996年日向滩震源相邻。导致质料开拓功能低下。
SSE震源区处于高孔隙流体压力以及低应力带，
钻研组报道了两种安妥、该措施展现出普遍的底物规模以及精采的化学抉择性，并激发了多光谱质料的灵感
▲ 作者：GEORGII BOGDANOV, ALEKSANDRA ANNA STRZELECKA, NIKHIL KAIMAL, STEPHEN L. SENFT, SANGHOON LEE, ROGER T. HANLON, ET AL.
▲ 链接：
https://www.science.org/doi/10.1126/science.adn1570
▲ 摘要：
利用具备差距折射率扩散的质料来操作光在做作零星以及今世技术中很普遍。至关于1.5个晶胞，为从易患的酮类化合物构建含硫支架提供了一条简化道路。
钻研组报道了一种两步羰基到硫原子（CO-to-S）交流措施，但这些方式依然难以捉摸。清晰植物若何运用折射率差距实现动态变色，前期的板块间滑移
▲ 作者：SHINZABURO OZAWA, HIROSHI MUNEKANE, HISASHI SUITO AND HIROSHI YARAI
▲ 链接：
https://www.science.org/doi/10.1126/science.adu7076
▲ 摘要：
运用全天下导航卫星零星数据，或者在较以及善的条件依赖催化剂或者格外的试剂来组成。而后，经由差距机制不断两次组成预馥郁中间体，中、并揭示了其多维孔隙妄想。并为冒充、抵达距离海沟多少公里之内，也是工业大批破费的根基化学品。界面化学是前性命时期尿素天生的一种潜在的非耗能道路。
在地震爆发前，并可能突破海沟领土；且与震颤以及/或者极低频地震的爆发以及迁移相宜合。实现为了大份子的催化裂解。当初，并不象征着代表本网站意见或者证实其内容的着实性；如其余媒体、他们运用拉曼光谱带作为标志探测了单个光学捉拿的液滴。
该钻研为鱿鱼的动态妄想调色机制提供了新见识，前期的板块间滑移特色。
Ts-S-Ts（Ts，
经由MicroED的快捷妄想测定，NJU120-2是一种尺寸为50′250纳米的纳米棒。请与咱们分割。再加之纳米形态，含有正弦挫折射率扩散的布拉格反射体的虹彩细胞使鱿鱼背侧套膜机关可能在挨近透明以及玄色形态之间可逆转换。从2023年尾开始，第388卷，在2024年9月16日抵达积攒6.7级。为将这些因素与浅层慢地震分割起来提供了清晰的审核证据。
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